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Recent progress on 2D metal carbide/nitride (MXene) nanocomposites for lithium-based batteries
FlatChem ( IF 5.9 ) Pub Date : 2021-09-02 , DOI: 10.1016/j.flatc.2021.100281
Oladipo Folorunso 1, 2 , Neeraj Kumar 2 , Yskandar Hamam 1, 3 , Rotimi Sadiku 4 , Suprakas Sinha Ray 2, 5
Affiliation  

This article provides an overview of the recent developments in 2D metal carbide/nitride (MXene) nanocomposites for lithium-based batteries to solve the continuing issues with energy storage. The results of numerous investigations on 2D-MXene show that MXene is flexible; mechanically strong; thermally and chemically stable; either hydrophilic, hydrophobic, or an admixture of both; and possesses excellent electrical conductivity and large surface area. The production processes, properties, and applications of 2D-MXene for energy storage are critically reviewed. We discovered that 2D-MXene is a promising lithium-ion battery electrode if its restacking issues are overcame. Moreover, hydroxylation and fluorination bonds in MXene inhibit the easy diffusion of lithium ions, leading to a decrease in battery capacity. Furthermore, the delamination of 2D-MXene layers, the tuning of the interlayer spacing, the introduction of vacancies, and surface modification are effective methods to enhance the performance of MXene for electrochemical applications. In addition, the choice of synthetic route and volume fraction are among the determining factors dictating the electrical conductivity of 2D-MXene-based composites. By considering the remarkable properties of 2D-MXene and 2D-MXene-based nanocomposites for energy storage, this study recommends their commercial production for lithium-ion battery anode electrodes.



中文翻译:

用于锂基电池的二维金属碳化物/氮化物(MXene)纳米复合材料的最新进展

本文概述了用于锂基电池的二维金属碳化物/氮化物 (MXene) 纳米复合材料的最新发展,以解决能源存储方面的持续问题。对 2D-MXene 的大量研究结果表明,MXene 是灵活的;机械强度高;热稳定性和化学稳定性;亲水性、疏水性或两者的混合物;并具有优良的导电性和大的表面积。对用于储能的 2D-MXene 的生产过程、性能和应用进行了严格审查。我们发现,如果克服了重新堆叠问题,2D-MXene 是一种很有前途的锂离子电池电极。此外,MXene中的羟基化和氟化键抑制了锂离子的容易扩散,导致电池容量下降。此外,2D-MXene 层的分层、层间距的调整、空位的引入和表面改性是提高 MXene 在电化学应用中的性能的有效方法。此外,合成路线和体积分数的选择是决定 2D-MXene 基复合材料导电性的决定因素之一。通过考虑用于储能的 2D-MXene 和基于 2D-MXene 的纳米复合材料的显着特性,本研究推荐了它们用于锂离子电池阳极电极的商业化生产。合成路线和体积分数的选择是决定 2D-MXene 基复合材料导电性的决定性因素。通过考虑用于储能的 2D-MXene 和基于 2D-MXene 的纳米复合材料的显着特性,本研究推荐了它们用于锂离子电池阳极电极的商业化生产。合成路线和体积分数的选择是决定 2D-MXene 基复合材料导电性的决定性因素。通过考虑用于储能的 2D-MXene 和基于 2D-MXene 的纳米复合材料的显着特性,本研究推荐了它们用于锂离子电池阳极电极的商业化生产。

更新日期:2021-09-09
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