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Ambimodal Transition States in Diels–Alder Cycloadditions of Tropolone and Tropolonate with N-Methylmaleimide**
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-09-01 , DOI: 10.1002/anie.202109608
Hong Zhang 1, 2 , Mathias Kirk Thøgersen 3 , Cooper S Jamieson 1 , Xiao-Song Xue 1 , Karl Anker Jørgensen 3 , Kendall N Houk 1
Affiliation  

The cycloaddition of tropolone with maleimide in the presence of weak base involves an ambimodal transition state that leads directly to both endo- and exo-adducts.
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中文翻译:

Tropolone 和 Tropolonate 与 N-甲基马来酰亚胺的 Diels-Alder 环加成反应中的双峰过渡态**

在弱碱存在马来酰亚胺酚酮的环加成涉及的ambimodal过渡状态直接导到两个内切-和-adducts。
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更新日期:2021-11-08
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