Reactions of benzyltriphenylphosphonium salts under photoredox catalysis,Organic & Biomolecular Chemistry

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Reactions of benzyltriphenylphosphonium salts under photoredox catalysis
Organic & Biomolecular Chemistry ( IF 2.9 ) Pub Date : 2021-08-26 , DOI: 10.1039/d1ob01570b
Andrew M Boldt ₁ , Sidney I Dickinson ₁ , Jonathan R Ramirez ₁ , Anna M Benz-Weeden ₁ , David S Wilson ₁ , Susan M Stevenson ₁

Affiliation

The development of benzyltriphenylphosphonium salts as alkyl radical precursors using photoredox catalysis is described. Depending on substituents, the benzylic radicals may couple to form C–C bonds or abstract a hydrogen atom to form C–H bonds. A natural product, brittonin A, was also synthesized using this method.

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