Nitrogen-rich tricyclic-based energetic materials,Materials Chemistry Frontiers

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Nitrogen-rich tricyclic-based energetic materials
Materials Chemistry Frontiers ( IF 6.0 ) Pub Date : 2021-08-17 , DOI: 10.1039/d1qm00916h
Jie Tang ₁ , Hongwei Yang ₁ , Yong Cui ₂ , Guangbin Cheng ₁

Affiliation

The chemistry of high-energy-density materials (HEDMs) featuring multiple nitrogen-rich heterocyclic skeletons with energetic fragments has witnessed enormous growth since the process of manufacturing explosives successfully was improved by Alfred Nobel. In particular, the recent surge of interest in HEDMs is because of its wide application in the military and civilian fields. In this review, we provide a systematic introduction to the developments in heterocyclic nitrogen-rich energetic materials with various explosive groups in the form of tricyclic-based compounds. This review summarizes the recent efforts toward new HEDMs based on the synthetic route, crystal behavior and the structure–property relationship. Further studies on new nitrogen-rich heterocycles may be helpful to achieve a more sustainable chemical process, which could make a positive impact of chemistry, not only for HEDMs, but also in other fields.

中文翻译：

富氮三环基含能材料

自从阿尔弗雷德·诺贝尔成功改进炸药的制造工艺以来，具有多个富氮杂环骨架和高能碎片的高能量密度材料 (HEDM) 的化学得到了巨大的发展。特别是，最近对 HEDM 的兴趣激增是因为它在军事和民用领域的广泛应用。在这篇综述中，我们系统地介绍了杂环富氮含能材料的发展，该材料具有三环类化合物形式的各种爆炸性基团。这篇综述总结了最近基于合成路线、晶体行为和结构-性能关系的新型 HEDM 的努力。对新的富氮杂环的进一步研究可能有助于实现更可持续的化学过程，

更新日期：2021-09-01

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