(1-Selenocyanatoethyl)benzene: A Selenocyanation Reagent for Site-Selective Selenocyanation of Inert Alkyl C(sp3)–H Bonds,Organic Letters

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(1-Selenocyanatoethyl)benzene: A Selenocyanation Reagent for Site-Selective Selenocyanation of Inert Alkyl C(sp3)–H Bonds
Organic Letters ( IF 4.9 ) Pub Date : 2021-09-01 , DOI: 10.1021/acs.orglett.1c02564
Fei Yu ₁ , Chuang Li ₁ , Chuangye Wang ₁ , Hongwei Zhang ₁ , Zhong-Yan Cao ₂

Affiliation

A new, simple, yet easily accessible, (1-selenocyanatoethyl)benzene has been designed and applied as a SeCN group transfer reagent for selenocyanation of aliphatic C(sp³)–H bonds for the first time. This protocol is featured with mild reaction conditions and wide substrate scope. Control experiments reveal that a radical-group transfer mechanism might be involved.

中文翻译：

(1-硒氰基乙基)苯：惰性烷基C(sp3)-H键的位点选择性硒氰化反应的硒氰化试剂

一种新的、简单但易于获得的（1-硒氰基乙基）苯已被设计并首次用作 SeCN 基团转移试剂，用于脂肪族 C(sp ³ )-H 键的硒氰化。该协议具有温和的反应条件和广泛的底物范围。对照实验表明可能涉及自由基转移机制。

更新日期：2021-09-17

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