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(1-Selenocyanatoethyl)benzene: A Selenocyanation Reagent for Site-Selective Selenocyanation of Inert Alkyl C(sp3)–H Bonds
Organic Letters ( IF 4.9 ) Pub Date : 2021-09-01 , DOI: 10.1021/acs.orglett.1c02564
Fei Yu 1 , Chuang Li 1 , Chuangye Wang 1 , Hongwei Zhang 1 , Zhong-Yan Cao 2
Affiliation  

A new, simple, yet easily accessible, (1-selenocyanatoethyl)benzene has been designed and applied as a SeCN group transfer reagent for selenocyanation of aliphatic C(sp3)–H bonds for the first time. This protocol is featured with mild reaction conditions and wide substrate scope. Control experiments reveal that a radical-group transfer mechanism might be involved.

中文翻译:

(1-硒氰基乙基)苯:惰性烷基C(sp3)-H键的位点选择性硒氰化反应的硒氰化试剂

一种新的、简单但易于获得的(1-硒氰基乙基)苯已被设计并首次用作 SeCN 基团转移试剂,用于脂肪族 C(sp 3 )-H 键的硒氰化。该协议具有温和的反应条件和广泛的底物范围。对照实验表明可能涉及自由基转移机制。
更新日期:2021-09-17
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