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Synthesis and modulation of multicolor fluorescent carbon dots from p-phenylenediamine and dansyl derivative for white light emitting diodes
Optical Materials ( IF 3.8 ) Pub Date : 2021-08-31 , DOI: 10.1016/j.optmat.2021.111502
L.B.O. Davi 1 , D.J.P. Lima 1 , C.D.A.E.S. Barbosa 1
Affiliation  

Carbon dots (C-dots) with multicolor emission are promising in the development of white light emitting diode (WLED) devices with high efficiency and low cost. In this study, we synthesized C-dots with tricolor emissions of blue (C-DsCl), green (C-pPDDS) and red (C-pPD) via the hydrothermal method using dansyl chloride, p-phenyldiaminadansyl and p-phenylenediamine as precursors, respectively. The fluorescent properties of the synthesized C-dots were found to be dependent on the presence of heteroatoms obtained via modulation of the p-phenylenediamine and dansyl chloride molecules, leading to an increased quantum yield for the N and S co-doped C-dots. The C-dots/PVP film displayed good CRI up to 89, CCT of 5628 K and color coordinates of (0.33, 0.31), close to that of pure white-light emission (0.33, 0.33). So, the C-dots with multicolor emission produced in this study can be used as a color converter to produce high-quality WLEDs.



中文翻译:

白光发光二极管用对苯二胺和丹酰衍生物的多色荧光碳点的合成和调制

具有多色发射的碳点(C-dots)在开发具有高效率和低成本的白光发光二极管(WLED)器件方面很有前景。在这项研究中,我们通过水热法使用丹磺酰氯、对苯二胺基和对苯二胺合成了具有蓝色 (C-DsCl)、绿色 (C- p PDDS) 和红色 (C- p PD)三色发射的碳点分别作为前体。发现合成的碳点的荧光特性取决于通过调节p获得的杂原子的存在-苯二胺和丹磺酰氯分子,导致 N 和 S 共掺杂 C 点的量子产率增加。C-dots/PVP薄膜显示出良好的CRI高达89,CCT为5628 K,色坐标为(0.33, 0.31),接近纯白光发射(0.33, 0.33)。因此,本研究中产生的具有多色发射的 C 点可以用作颜色转换器来生产高质量的 WLED。

更新日期:2021-09-01
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