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Poly(lactic acid)-Based Film with Excellent Thermal Stability for High Energy Density Capacitor Applications
Macromolecular Materials and Engineering ( IF 3.9 ) Pub Date : 2021-09-01 , DOI: 10.1002/mame.202100402
Yonggui Wang 1, 2 , Jinxi Zhang 2 , Bowen Zhang 2 , Kailiang Ren 1, 2
Affiliation  

Dielectric capacitors play a key role in high power electronics, electric vehicles, and medical devices. Due to the biodegradability, high thermal stability, and ease of processing, poly(lactic acid)-based (PLA) films are widely used in applications of tissue engineering, actuators, and sensors. In this investigation, PLA films are prepared using a solution casting method for high energy density capacitor applications. It is found that the stretched poly(d-lactic acid) (PDLA) film exhibits an energy density and charge discharge efficiency of 18.5 J cm−3 and 95%, respectively, at room temperature. Furthermore, after a heating time of 30 min at 100 °C, it is found that the energy density and chargedischarge efficiency of the stretched PDLA films are maintained at 11.2 J cm−3 and 76%, respectively. In comparison, the energy density and efficiency of the stretched PDLA film are 1.03-fold and 53% higher, respectively, than those of the stretched poly(vinylidene fluoride-hexafluoropropylene) film at 100 °C with the same heat treatment. Compared with a high temperature polyimide material, the energy density of the stretched PDLA film is 1.98-fold higher at 100 °C. The PLA-based material shows great promise for application in high energy density capacitors operating at a high temperature (100 °C).

中文翻译:

具有优异热稳定性的聚乳酸基薄膜,适用于高能量密度电容器应用

介电电容器在大功率电子产品、电动汽车和医疗设备中发挥着关键作用。由于可生物降解、高热稳定性和易于加工,聚乳酸基 (PLA) 薄膜被广泛用于组织工程、执行器和传感器的应用中。在这项研究中,PLA 薄膜是使用溶液浇铸方法制备的,用于高能量密度电容器应用。发现拉伸的聚(d-乳酸)(PDLA)膜在室温下分别表现出18.5 J cm -3和95%的能量密度和充电放电效率。此外,在 100°C 下加热 30 分钟后,发现拉伸的 PDLA 薄膜的能量密度和充放电效率保持在 11.2 J cm-3和 76%,分别。相比之下,拉伸后的 PDLA 薄膜在 100 °C 下相同热处理的能量密度和效率分别比拉伸的聚(偏二氟乙烯-六氟丙烯)薄膜高 1.03 倍和 53%。与高温聚酰亚胺材料相比,拉伸后的 PDLA 薄膜在 100°C 时的能量密度提高了 1.98 倍。PLA 基材料在高温 (100 °C) 下工作的高能量密度电容器中显示出巨大的应用前景。
更新日期:2021-09-01
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