Intramolecular Alkene–Alkene Coupling via Rh(III)-Catalyzed Alkenyl sp2 C–H Functionalization: Divergent Pathways to Indene or α-Naphthol Derivatives,ACS Catalysis

当前位置： X-MOL 学术 › ACS Catal. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Intramolecular Alkene–Alkene Coupling via Rh(III)-Catalyzed Alkenyl sp2 C–H Functionalization: Divergent Pathways to Indene or α-Naphthol Derivatives
ACS Catalysis ( IF 11.3 ) Pub Date : 2021-09-01 , DOI: 10.1021/acscatal.1c03175
Manikantha Maraswami ₁ , Thomas Diggins ₂ , Jeffrey Goh ₁ , Raymond Tio ₁ , Wan Qing Renee Ong ₁ , Hajime Hirao ₃ , Teck-Peng Loh ₁

Affiliation

Highly selective synthesis of either indene or 1-naphthol derivatives through intramolecular alkene–alkene cross-coupling is reported. The reaction works with different alkene pairs that couple to give the corresponding products in good to satisfactory yields. The indene products of our reaction also allow further derivatization. The reaction pathway is dependent on alkene functionalities.

中文翻译：

通过 Rh(III)-催化的烯基 sp2 C-H 功能化实现分子内烯烃 - 烯烃偶联：茚或 α-萘酚衍生物的不同途径

报道了通过分子内烯烃 - 烯烃交叉偶联高选择性合成茚或 1-萘酚衍生物。该反应与不同的烯烃对结合，以良好到令人满意的产率得到相应的产物。我们反应的茚产物也允许进一步衍生化。反应途径取决于烯烃官能度。

更新日期：2021-09-17

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11