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Temperature Effect on Early Oxidation Behavior of NiCoCrAlY Coatings: Microstructure and Phase Transformation
Acta Metallurgica Sinica-English Letters ( IF 2.9 ) Pub Date : 2021-09-01 , DOI: 10.1007/s40195-021-01310-5
A. Ullah 1, 2 , A. Khan 1, 3 , Z. B. Bao 2 , M. M. Xu 2 , S. L. Zhu 2 , Y. F. Yang 4 , F. H. Wang 5
Affiliation  

Initial oxidation behavior of NiCoCrAlY coating prepared by arc-ion plating has been studied in air at 900, 1000 and 1100 °C. The results showed that phase transformation from transient θ-Al2O3 to α-Al2O3 was highly related to the temperature and oxidation time. The oxide scale in the initial stage was mainly composed of θ-Al2O3 at 900 °C. Instead, more amount of α-Al2O3 emerged out with increasing oxidation temperature. The elemental distribution after oxidation confirmed that faster chromium diffusion to the oxide scale played an important role in the speedy transformation from θ-Al2O3 to α-Al2O3. Y segregation at scale/coating interface resulted in less cavity formation and hence improved the oxide scale adherence.



中文翻译:

温度对 NiCoCrAlY 涂层早期氧化行为的影响:微观结构和相变

研究了电弧离子镀制备的 NiCoCrAlY 涂层在 900、1000 和 1100 °C 空气中的初始氧化行为。结果表明,从瞬态θ-Al 2 O 3到α-Al 2 O 3 的相变与温度和氧化时间高度相关。初始阶段的氧化皮主要由 θ-Al 2 O 3组成,温度为 900 ℃。相反,随着氧化温度的升高,出现了更多的α-Al 2 O 3。氧化后的元素分布证实,更快的铬扩散到氧化皮在 θ-Al 2 O 3的快速转变中起重要作用α-Al 2 O 3。氧化皮/涂层界面处的 Y 偏析导致较少的空腔形成,因此提高了氧化皮的附着力。

更新日期:2021-09-01
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