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Exploration on χ-Anderson type Polyoxometalates based hybrids towards photovoltaic response in solar cell
Inorganic Chemistry Communications ( IF 4.4 ) Pub Date : 2021-08-31 , DOI: 10.1016/j.inoche.2021.108875
Muhammad Ali Khan 1 , Zainab Shakoor 2 , Talal Akhtar 1 , Muhammad Sajid 1 , Hafiz Muhammad Asif 1
Affiliation  

Two polymerized χ-Anderson type Polyoxometalates based hybrids [N(C4H9)4]3[C(CH2O)3Zn Mo6O18C(CH2O)3CH2OCH2] and [N(C4H9)4]3[C(CH2O)3ZnMo6O18C(CH2O)3(CH2OCH2)2C (CH2OH)2] named as (TBA)3[CA-Di@POM] and (TBA)3[CA-Tri@POM ], respectively have been prepared and different techniques such as FTIR, NMR(1H, 13C) and mass spectrometry were used to characterize these hybrids. Moreover, their photovoltaic performance in solar cell have been explored through current–voltage (I-V) curve. Different photochemical parameters such as short circuit current (ISC), open circuit voltage (VOC), fill factor (FF) and efficiency (η) were measured from I to V curve and compared with literature. It is indicated from these results that there is notable enhancement in the efficiency of (TBA)3[CA-Di@POM] and (TBA)3[CA-Tri@POM] films in solar cell which were calculated as 0.58% and 1.25% respectively.



中文翻译:

基于 χ-Anderson 型多金属氧酸盐的杂化物对太阳能电池光伏响应的探索

两种聚合的基于 χ-Anderson 型多金属氧酸盐的杂化物 [N(C 4 H 9 ) 4 ] 3 [C(CH 2 O) 3 Zn Mo 6 O 18 C(CH 2 O) 3 CH 2 OCH 2 ] 和 [N(C) 4 H 9 ) 4 ] 3 [C(CH 2 O) 3 ZnMo 6 O 18 C(CH 2 O) 3 (CH 2 OCH 2 ) 2 C (CH 2 OH)2 ] 分别命名为 (TBA) 3 [CA-Di@POM] 和 (TBA) 3 [CA-Tri@POM ],分别制备了 FTIR、NMR( 1 H, 13 C) 和质谱等不同技术被用来表征这些杂种。此外,通过电流-电压(IV)曲线探索了它们在太阳能电池中的光伏性能。从 I 到 V 曲线测量不同的光化学参数,如短路电流 (I SC )、开路电压 (V OC )、填充因子 (FF) 和效率 (η) 并与文献进行比较。这些结果表明(TBA) 3 [CA-Di@POM] 和(TBA) 3的效率显着提高太阳能电池中的 [CA-Tri@POM] 薄膜分别计算为 0.58% 和 1.25%。

更新日期:2021-09-02
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