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Highly dispersed CeO2–x nanoparticles with rich oxygen vacancies enhance photocatalytic performance of g-C3N4 toward methyl orange degradation under visible light irradiation
Journal of Rare Earths ( IF 5.2 ) Pub Date : 2021-08-30 , DOI: 10.1016/j.jre.2021.08.013
Xuejun Xu 1, 2 , Tianhua Huang 1, 2 , Yisheng Xu 1, 2 , Huawen Hu 1, 2 , Shuang Liao 1, 2 , Xiaohong Hu 1, 2 , Dongchu Chen 1, 2 , Min Zhang 1, 2
Affiliation  

CeO2/g-C3N4 photocatalysts have attracted tremendous attention in the photocatalytic degradation of organic pollutants. The design and construction of highly active CeO2/g-C3N4 photocatalysts without harsh conditions are still challenging. Herein, highly dispersed CeO2–x nanoparticles with rich oxygen vacancies were successfully precipitated on the surface of g-C3N4 under mild conditions. The fabricated CeO2–x/g-C3N4 exhibits remarkable activity and stability for photocatalytic degradation of MO pollutant. The optimal rate constant of MO degradation over CeO2–x/g-C3N4 is about 0.031 min−1, which is three times higher than that of g-C3N4. A negligible activity decrease is observed after three cycling runs. The enhanced catalytic performance can be ascribed to the excellent dispersion of CeO2–x with rich oxygen vacancies that benefit O2 adsorption and visible light absorption. In addition, the proper band alignment between CeO2–x and g-C3N4 is conducive to the highly efficient separation of photogenerated electron–hole pairs.



中文翻译:

具有丰富氧空位的高度分散的CeO2-x纳米粒子增强了可见光照射下g-C3N4对甲基橙降解的光催化性能

CeO 2 /gC 3 N 4光催化剂在光催化降解有机污染物方面引起了极大的关注。没有苛刻条件的高活性CeO 2 /gC 3 N 4光催化剂的设计和构建仍然具有挑战性。在此,具有丰富氧空位的高度分散的CeO 2- x纳米粒子在温和条件下成功地沉淀在gC 3 N 4的表面上。制备的CeO 2– x /gC 3 N 4对MO污染物的光催化降解具有显着的活性和稳定性。在CeO 2- x /gC 3 N 4上MO降解的最佳速率常数约为0.031 min -1 ,是gC 3 N 4的三倍。在三个循环运行后观察到可忽略不计的活动减少。增强的催化性能可归因于具有丰富氧空位的 CeO 2- x的出色分散,有利于 O 2吸附和可见光吸收。此外,CeO 2– x和 gC 3 N 4之间的正确能带排列有利于光生电子-空穴对的高效分离。

更新日期:2021-08-30
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