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Black Phosphorene Modified Electrochemical Sensor for Fast Determination of 5-Hydroxymethyl-2-furfural in Milk
Electroanalysis ( IF 2.7 ) Pub Date : 2021-08-30 , DOI: 10.1002/elan.202100302
yuzhen Li 1 , Lu Huang 2 , Xuexiang Weng 3 , Zhenmin Liu 4 , Chunping You 5
Affiliation  

The fast detection of 5-hydroxymethyl-2-furfural (HMF) in food industry is vital because of its toxicity and mutagenicity. A glassy carbon electrode (GCE) modified with black phosphorene (BP) nanosheets was prepared and coated with Nafion to improve stability. The electrode has excellent electrochemical stability and current response for HMF electroreduction. The good linear relationship is in the concentration range of 0.1–10 μg/mL with the detection limit of 0.012 μg/mL. HMF electroreduction is a diffusion-controlled process involving two electrons and two protons. The sensor was successfully applied to the measurement of HMF in milk with the recovery values of 92.92 %–96.33 %.

中文翻译:

用于快速测定牛奶中 5-羟甲基-2-糠醛的黑色磷烯修饰电化学传感器

食品工业中 5-羟甲基-2-糠醛 (HMF) 的快速检测至关重要,因为它具有毒性和致突变性。制备了用黑色磷烯 (BP) 纳米片改性的玻碳电极 (GCE) 并涂上 Nafion 以提高稳定性。该电极对 HMF 电还原具有优异的电化学稳定性和电流响应。在 0.1–10 μg/mL 的浓度范围内具有良好的线性关系,检测限为 0.012 μg/mL。HMF 电还原是涉及两个电子和两个质子的扩散控制过程。该传感器成功应用于牛奶中 HMF 的测量,回收率为 92.92%–96.33%。
更新日期:2021-08-30
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