The kinetics of organic reactions of different types in microvolumes (droplets, thin films, and sealed tubes) show effects of gas/solution interfacial area, reaction molecularity and solvent polarity. Partial solvation at the gas/solution interface is a major contributor to the 10⁴-fold reaction acceleration seen in bimolecular but not unimolecular reactions in microdroplets. Reaction acceleration can be used to manipulate selectivity by solvent choice.

中文翻译：

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气体/溶液界面的部分溶剂化促进反应加速

微体积（液滴、薄膜和密封管）中不同类型的有机反应的动力学显示了气体/溶液界面面积、反应分子和溶剂极性的影响。气体/溶液界面处的部分溶剂化是微滴中双分子而非单分子反应中所见的 10 ⁴倍反应加速的主要贡献者。反应加速可用于通过溶剂选择来控制选择性。