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Development and optimization of Zn–Ni–TiO2 composite coating, assessment of its corrosion resistance and antimicrobial activity
Applied Nanoscience ( IF 3.869 ) Pub Date : 2021-08-27 , DOI: 10.1007/s13204-021-02029-6
Vinayaka B. Shet 1 , Guru Prasad 1 , Amogh Kodgi 1 , Anurag Damodaran 1 , Akshara Savithri 1 , Ramesh S. Bhat 2 , Raja Selvaraj 3
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Zn–Ni–TiO2 composite coating was developed through response surface methodology. The current density and concentration of TiO2 were optimized to obtain a minimum corrosion rate. The optimized condition obtained from the central composite design achieved a minimum experimental corrosion rate of 0.122 mm/year as a response for the Zn–Ni–TiO2 composite coating with a current density of 2.91 A/dm2 and concentration of TiO2 4.9 g/L. The potentiodynamic polarization and electrochemical impedance spectroscopic method was used to measure the corrosion resistance. The antimicrobial activity of the composite coating was assessed. Growth of Gram-negative and -positive microbes was observed on the polished mild steel. However, the composite coating exhibited resistance to Gram-negative microorganisms. Surface characterization was carried out using scanning electron microscopy (SEM) along with energy-dispersive X-ray spectroscopy depicting the presence of Zn, Ni, Ti, and O elements in the composite coating. Atomic force microscopy confirmed the surface roughness and heterogeneous distribution of crystal grain.



中文翻译:

Zn-Ni-TiO2复合涂层的开发和优化,评估其耐腐蚀性和抗菌活性

Zn-Ni-TiO 2复合涂层是通过响应面方法开发的。优化电流密度和TiO 2浓度以获得最小腐蚀速率。从中心复合设计获得的优化条件实现了 0.122 毫米/年的最小实验腐蚀速率,作为对电流密度为 2.91 A/dm 2和 TiO 2浓度的 Zn-Ni-TiO 2复合涂层的响应4.9 克/升。动电位极化和电化学阻抗光谱法用于测量耐腐蚀性。评估复合涂层的抗菌活性。在抛光的低碳钢上观察到革兰氏阴性和阳性微生物的生长。然而,复合涂层表现出对革兰氏阴性微生物的抗性。使用扫描电子显微镜 (SEM) 以及描述复合涂层中存在的 Zn、Ni、Ti 和 O 元素的能量色散 X 射线光谱仪进行表面表征。原子力显微镜证实了晶粒的表面粗糙度和不均匀分布。

更新日期:2021-08-27
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