Vicinal Trifluoromethylthioamination of Alkenes with Trifluoromethanesulfenamides,Asian Journal of Organic Chemistry

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Vicinal Trifluoromethylthioamination of Alkenes with Trifluoromethanesulfenamides
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-08-26 , DOI: 10.1002/ajoc.202100553
Arunachalam Kesavan ₁ , Pazhamalai Anbarasan ₂

Affiliation

BF₃ ⋅ OEt₂ meidated vicinal trifluoromethylthioamination of alkenes has been accomplished using trifluoromethanesulfenamides at room temperature. Trifluoromethanesulfenamides play dual role as ‘SCF₃’ and amine source, which allows high atom-efficient approach to access 1-trifluoromethylthio-2-aminoalkane derivatives.