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Interfacial adsorption of nanoparticles of maltodextrin for enhanced protection of metal surface
Surfaces and Interfaces ( IF 5.7 ) Pub Date : 2021-08-27 , DOI: 10.1016/j.surfin.2021.101418
Mikitha Pais 1 , Sajan D. George 2, 3 , Padmalatha Rao 1
Affiliation  

In recent years, application of nanoparticles in various fields of physical science and natural science receiving tremendous attention from researchers. Nanoparticles can offer significant advantages in terms of high stability, enhanced mechanical properties, and high surface area to volume ratio. This work attempts to explore these noble characteristic properties of nanoparticles for preservation for materials of engineering applications. Nanoparticles of maltodextrin (MLD-Np) were prepared by microwave-mediated nanoprecipitation technique. Characterization was done by spectral, zeta potential measurement, X-ray studies, Scanning Electron Microscope (SEM) and Transmission Electron Microscopy (TEM) analysis. In the second part, these nanoparticles were tested for their surface protection ability due to interfacial adsorption. Corrosion inhibition study measurements were done by electrochemical methods, and interfacial adsorption of inhibitor was established by studying surface morphology. The efficacy of these nanoparticles was 93% for the addition of 50 ppm of it. In the last part of this work, an attempt is made to compare the inhibiting ability of various reported chemical inhibitors for acid corrosion of zinc with synthesized nanoparticles. Nanoparticles of maltodextrin emerged as an appreciably good green corrosion inhibitor with environmental and economic benefits.



中文翻译:

麦芽糊精纳米颗粒的界面吸附增强金属表面保护

近年来,纳米粒子在物理科学和自然科学各个领域的应用受到了研究人员的极大关注。纳米颗粒在高稳定性、增强的机械性能和高表面积体积比方面具有显着优势。这项工作试图探索纳米粒子的这些高贵特性,以用于工程应用材料的保存。通过微波介导的纳米沉淀技术制备了麦芽糖糊精(MLD-Np)纳米颗粒。通过光谱、zeta 电位测量、X 射线研究、扫描电子显微镜 (SEM) 和透射电子显微镜 (TEM) 分析进行表征。在第二部分中,测试这些纳米颗粒由于界面吸附而产生的表面保护能力。通过电化学方法进行腐蚀抑制研究测量,并通过研究表面形态来建立抑制剂的界面吸附。添加 50 ppm 时,这些纳米颗粒的功效为 93%。在本工作的最后部分,尝试比较各种已报道的化学抑制剂对锌酸腐蚀的抑制能力与合成纳米颗粒。麦芽糖糊精纳米颗粒作为一种非常好的绿色缓蚀剂出现,具有环境和经济效益。尝试比较各种已报道的化学抑制剂对锌酸腐蚀的抑制能力与合成的纳米粒子。麦芽糖糊精纳米颗粒作为一种非常好的绿色缓蚀剂出现,具有环境和经济效益。尝试比较各种已报道的化学抑制剂对锌酸腐蚀的抑制能力与合成的纳米粒子。麦芽糖糊精纳米颗粒作为一种非常好的绿色缓蚀剂出现,具有环境和经济效益。

更新日期:2021-09-01
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