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Gold-Catalyzed Transformation of Ynamides
The Chemical Record ( IF 7.0 ) Pub Date : 2021-08-25 , DOI: 10.1002/tcr.202100159 Shashank Shandilya 1 , Manash Protim Gogoi 1 , Shubham Dutta 1 , Akhila K Sahoo 1
The Chemical Record ( IF 7.0 ) Pub Date : 2021-08-25 , DOI: 10.1002/tcr.202100159 Shashank Shandilya 1 , Manash Protim Gogoi 1 , Shubham Dutta 1 , Akhila K Sahoo 1
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Ynamide, a unique species with inherited polarization of nitrogen lone pair electron to triple bond, has been largely used for the developement of novel synthetic methods and the construction of unusual N-bearing heterocycles. The reaction versatility of ynamide on umpolung reactivity, radical reactions and asymmetric synthesis have been recently reviewed. This review provides an overall scenic view into the gold catalyzed transformation of ynamides. The ynamides reactivity towards nitrogen-transfer reagents, such as azides, nitrogen ylides, isoxazoles, and anthranils; oxygen atom-transfer reagents, like nitrones, sulfoxides, and pyridine N-oxides; and carbon nucleophiles under gold catalysis are herein uncovered. The scope as well the mechanistic insights of each reaction is also briefed.
中文翻译：
酰胺的金催化转化
Ynamide 是一种独特的物种，具有氮孤对电子到三键的遗传极化，已被广泛用于开发新的合成方法和构建不寻常的含氮杂环。最近综述了 ynamide 在 umpolung 反应性、自由基反应和不对称合成方面的反应多功能性。这篇综述提供了对 ynamides 的金催化转化的整体看法。ynamides 对氮转移试剂有反应性，例如叠氮化物、氮叶立德、异恶唑和邻氨基苯甲酸；氧原子转移试剂，如硝酮、亚砜和吡啶N-氧化物；金催化下的碳亲核试剂和碳亲核试剂在本文中未被发现。还简要介绍了每个反应的范围和机理见解。
更新日期：2021-08-25
中文翻译：
酰胺的金催化转化
Ynamide 是一种独特的物种，具有氮孤对电子到三键的遗传极化，已被广泛用于开发新的合成方法和构建不寻常的含氮杂环。最近综述了 ynamide 在 umpolung 反应性、自由基反应和不对称合成方面的反应多功能性。这篇综述提供了对 ynamides 的金催化转化的整体看法。ynamides 对氮转移试剂有反应性，例如叠氮化物、氮叶立德、异恶唑和邻氨基苯甲酸；氧原子转移试剂，如硝酮、亚砜和吡啶N-氧化物；金催化下的碳亲核试剂和碳亲核试剂在本文中未被发现。还简要介绍了每个反应的范围和机理见解。
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