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Rare-earth functioned Bi2WO6 nanofibers via electrospinning: Boosted catalytic performance and contact-free temperature monitoring on degradation process
Colloid and Interface Science Communications ( IF 4.7 ) Pub Date : 2021-08-25 , DOI: 10.1016/j.colcom.2021.100494
Zhewei Liu 1 , Lifan Shen 2 , Xiaoyang He 1 , Edwin Yue Bun Pun 3 , Hai Lin 1, 3
Affiliation  

Bi2WO6: Er, Yb nanofibers prepared via solvothermal-electrospinning method have high-efficiency photocatalysis performance and superior temperature feedback. Combining crystal integrity and polymer processability, polyacrylonitrile composite fibers are commendable in many aspects, such as large specific surface area, excellent flexibility, controllable structure and high solar energy utilization. The boost in photocatalysis activity can be attributable to non-radiative energy transfer between Er3+ ions with bismuth tungstate and doping effect of rare earth ions in Bi2WO6, where this doping enhances separation efficiency of electron-hole pairs and promotes generation of highly oxidative species. The electrospun nanofibers also can accurately perform contact-free temperature monitoring and real-time thermal feedback on the degradation system through 2H11/2 → 4I15/2 and 4S3/2 → 4I15/2 radiation transitions of Er3+ ions. In addition, the absolute sensitivity SA and the relative sensitivity SR are as high as 0.868% K−1 and 1.548% K−1 at 313 K, respectively, which indicates nanofibers have good thermal sensitivity. This dual-function nanofiber provides new application prospects for the development of innovative multifunctional semiconductor materials to cope with the ecological and energy crisis.



中文翻译:

稀土功能Bi2WO6纳米纤维通过静电纺丝:提高催化性能和降解过程的非接触温度监测

Bi 2 WO 6 : 溶剂热-静电纺丝法制备的Er、Yb纳米纤维具有高效的光催化性能和优异的温度反馈。聚丙烯腈复合纤维结合晶体完整性和聚合物可加工性,在比表面积大、柔韧性好、结构可控和太阳能利用率高等方面值得称道。光催化活性的提高可归因于 Er 3+离子与钨酸铋之间的非辐射能量转移以及稀土离子在 Bi 2 WO 6 中的掺杂作用,这种掺杂提高了电子 - 空穴对的分离效率并促进了高氧化性物质的产生。电纺纳米纤维还可以通过Er 的2 H 11/2  →  4 I 15/24 S 3/2  →  4 I 15/2辐射跃迁对降解系统进行准确的非接触式温度监测和实时热反馈3+离子。此外,绝对灵敏度S和相对灵敏度S - [R是高达0.868%K -1和1.548%K -1分别在 313 K,这表明纳米纤维具有良好的热灵敏度。这种双功能纳米纤维为开发创新的多功能半导体材料以应对生态和能源危机提供了新的应用前景。

更新日期:2021-08-26
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