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Synthesis and luminescence properties of Pr3+ ion-doped Ba3Y(PO4)3 phosphors
Luminescence ( IF 3.2 ) Pub Date : 2021-08-26 , DOI: 10.1002/bio.4135
Megala Rajesh, Mudavat Srinivas, Nannepaga John Sushma, Tata Sanjay Kanna Sharma, Koduru Mallikarjuna, Borelli Deva Prasad Raju

Barium yttrium phosphate (BYP) phosphor doped with trivalent praseodymium ions (BaY(1−x)(PO4)3:Pr3+ (x = 0, 0.01, 0.05, 0.1, 0.15, and 0.2 wt%) was synthesized using a high temperature solid-state reaction method. Structural properties were analyzed through X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. XRD patterns confirmed the structure of the synthesized phosphor and average crystalline size was estimated (approximately 63.8 Å). Vibrational functional groups were identified using FTIR spectroscopy. The emission spectrum was recorded under an 444 nm excitation wavelength, which showed various emission transitions of Pr3+ ions. Commission Internationale de l'éclairage coordinates, colour purity, and colour correlated temperature values were calculated for the BYP:Pr3+ phosphors and these coordinate values fell in the yellow region of the visible spectrum.

中文翻译:

Pr3+离子掺杂Ba3Y(PO4)3荧光粉的合成及发光性能

使用三价镨离子(BaY (1-x) (PO 4 ) 3 :Pr 3+ (x = 0, 0.01, 0.05, 0.1, 0.15, and 0.2 wt%))合成了掺杂三价镨离子的磷酸钇钡(BYP)磷光体高温固相反应法。通过 X 射线衍射 (XRD) 和傅里叶变换红外 (FTIR) 光谱分析结构特性。XRD 图案证实了合成磷光体的结构,并估计了平均晶体尺寸(约 63.8 Å)。使用FTIR光谱识别振动官能团,在444 nm激发波长下记录发射光谱,显示Pr 3+ 的各种发射跃迁离子。计算了 BYP:Pr 3+荧光粉的Commission Internationale de l'éclairage 坐标、色纯度和颜色相关温度值,这些坐标值落在可见光谱的黄色区域内。
更新日期:2021-08-26
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