A Potential Iterative Approach to 1,4-Dihydro-N-Heteroacene Arrays,ChemistryOpen

当前位置： X-MOL 学术 › Chemistryopen › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

A Potential Iterative Approach to 1,4-Dihydro-N-Heteroacene Arrays
ChemistryOpen ( IF 2.5 ) Pub Date : 2021-08-25 , DOI: 10.1002/open.202100150
M John Plater ₁ , William T A Harrison ₁

Affiliation

N-Butyl-5-methyl-3-nitro-5,10-dihydrophenazine has been prepared and its solid-state structure was characterised by an X-Ray single crystal structure determination. Its potential use for an iterative synthesis of 1,4-dihydro-N-heteroacenes is discussed. A rationale for the successful synthesis of 5-methyl-2,3-dinitro-5,10-dihydrophenazine from two available precursors, its thermal instability in CH₂Cl₂ and its photochemical rearrangement to 10-methyl-3-nitrophenazin-2-(10H)-one are discussed.

中文翻译：

1,4-二氢-N-杂并苯阵列的潜在迭代方法

制备了N-丁基-5-甲基-3-硝基-5,10-二氢吩嗪，并通过X射线单晶结构测定对其固态结构进行了表征。讨论了其在 1,4-二氢-N-杂并苯迭代合成中的潜在用途。从两种可用前体成功合成 5-甲基-2,3-二硝基-5,10-二氢吩嗪的基本原理、其在 CH ₂ Cl ₂中的热不稳定性及其光化学重排为 10-甲基-3-硝基吩嗪-2- (10 H )-一进行了讨论。

更新日期：2021-08-25

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11