Hierarchically Porous Metal–Organic Framework/MoS2 Interface for Selective Photocatalytic Conversion of CO2 with H2O into CH3COOH,Angewandte Chemie International Edition

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Hierarchically Porous Metal–Organic Framework/MoS2 Interface for Selective Photocatalytic Conversion of CO2 with H2O into CH3COOH
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2021-08-25 , DOI: 10.1002/anie.202108892
Fengyang Yu ₁ , Xu Jing ₁ , Yao Wang ₁ , Mingyang Sun ₁ , Chunying Duan ₁

Affiliation

MoS₂ nanosheets were integrated into a hierarchically porous defective MOF UiO-66. The unsaturated Mo atoms in MoS₂ sheets rationally regulate contact interfaces with Zr₆O₄(OH)₄ nodes to form Mo-O-Zr bimetallic sites. The Mo-O-Zr bimetallic sites at the interfaces allow photo-catalytic conversion of gas phase CO₂ and H₂O into CH₃COOH and O₂.

中文翻译：

用于将 CO2 与 H2O 选择性光催化转化为 CH3COOH 的分级多孔金属-有机骨架/MoS2 界面

MoS ₂纳米片被集成到分层多孔的有缺陷的 MOF UiO-66 中。MoS ₂片中的不饱和Mo原子合理地调节与Zr ₆ O ₄ (OH) ₄节点的接触界面以形成Mo-O-Zr双金属位点。界面处的 Mo-O-Zr 双金属位点允许气相 CO ₂和 H ₂ O光催化转化为 CH ₃ COOH 和 O ₂。

更新日期：2021-08-25

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