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Solution-Processable Multi-Substituted Buckybowls: Synthesis of Diindeno(1,2,3,4-defg:1’,2’,3’,4’-mnop)chrysene Derivatives
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-08-25 , DOI: 10.1002/ejoc.202100869 Naoki Yoshida 1 , Ryuhei Akasaka 1 , Yusuke Awakura 1 , Toru Amaya 2 , Tetsuo Iwasawa 3
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2021-08-25 , DOI: 10.1002/ejoc.202100869 Naoki Yoshida 1 , Ryuhei Akasaka 1 , Yusuke Awakura 1 , Toru Amaya 2 , Tetsuo Iwasawa 3
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Synthesis of an underrepresented buckybowl is described, including a description of its potent reactivities. The key to success is to readily prepare a tetra-brominated and highly-distorted precursor of dibenzo[g,p]chrysenes. The precursor undertook intra-molecular cyclization to form double pentagons, giving a gram-scale buckybowl skeleton, namely diindeno(1,2,3,4-defg:1’,2’,3’,4’-mnop)chrysene.
中文翻译：
可溶液加工的多取代巴基碗：二茚(1,2,3,4-defg:1',2',3',4'-mnop)chrysene 衍生物的合成
描述了代表性不足的巴基碗的合成，包括对其有效反应性的描述。成功的关键是容易地制备四溴化和高度扭曲的二苯并[ g , p ]芘的前体。前体进行分子内环化形成双五边形，得到克级巴基碗骨架，即二茚( 1,2,3,4-defg :1',2',3', 4'-mnop ) chrysene。
更新日期：2021-10-08
中文翻译：
可溶液加工的多取代巴基碗：二茚(1,2,3,4-defg:1',2',3',4'-mnop)chrysene 衍生物的合成
描述了代表性不足的巴基碗的合成，包括对其有效反应性的描述。成功的关键是容易地制备四溴化和高度扭曲的二苯并[ g , p ]芘的前体。前体进行分子内环化形成双五边形，得到克级巴基碗骨架，即二茚( 1,2,3,4-defg :1',2',3', 4'-mnop ) chrysene。
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