Indium-mediated allylation of carbonyl compounds in deep eutectic solvents,Applied Organometallic Chemistry

当前位置： X-MOL 学术 › Appl. Organomet. Chem. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Indium-mediated allylation of carbonyl compounds in deep eutectic solvents
Applied Organometallic Chemistry ( IF 3.7 ) Pub Date : 2021-08-25 , DOI: 10.1002/aoc.6418
Nerea González‐Gallardo ₁ , Beatriz Saavedra ₁ , Gabriela Guillena ₁ , Diego J. Ramón ₁

Affiliation

This study describes, for the first time, the in situ generation of indium organometallic reagents in environmentally friendly deep eutectic solvents (DESs). The allylation process of different carbonyl compounds is achieved mediated by indium metal and using cheap allyl chloride derivatives. The unique DES properties allow to perform the reaction at room temperature and under air, obtaining yields ranging from 45% to 99%. It is possible to recycle the reaction medium for at least four consecutive cycles without much decrease of the observed results. Also, a linear correlation between the yield of the reaction and the density of the DESs is observed.

中文翻译：

在低共熔溶剂中铟介导的羰基化合物烯丙基化

这项研究首次描述了在环境友好的低共熔溶剂 (DESs) 中原位生成铟有机金属试剂。不同羰基化合物的烯丙基化过程是通过金属铟和使用廉价的烯丙基氯衍生物来实现的。独特的 DES 特性允许在室温和空气下进行反应，获得 45% 到 99% 的产率。可以将反应介质循环至少四个连续循环，而不会显着降低观察到的结果。此外，还观察到反应产率与 DES 密度之间的线性相关性。

更新日期：2021-08-25

点击分享查看原文

点击收藏

公开下载

阅读更多本刊最新论文本刊介绍/投稿指南11