Cover Feature: Synthesis and Characterization of a Cobalt(III) Corrole with an S-Bound DMSO Ligand (Eur. J. Inorg. Chem. 35/2021),European Journal of Inorganic Chemistry

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Cover Feature: Synthesis and Characterization of a Cobalt(III) Corrole with an S-Bound DMSO Ligand (Eur. J. Inorg. Chem. 35/2021)
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2021-08-24 , DOI: 10.1002/ejic.202100696
Nicolás I. Neuman _{1,

2} , Arijit Singha Hazari ₁ , Julia Beerhues ₁ , Fabio Doctorovich ₃ , Santiago E. Vaillard ₂ , Biprajit Sarkar ₁

Affiliation

The Cover Feature shows the first reported molecular structure of an S-bound DMSO-ligated cobalt corrole, with a remarkably short Co-S bond length, as well as the frontier orbitals employed in multiconfigurational wavefunction calculations. These reveal that a σ-donor effect from the S atom is responsible for a closed-shell ground state configuration. The authors intimately combined experimental and theoretical techniques to elucidate aspects of the electronic structure and spectroscopic properties of this complex. More information can be found in the Full Paper by N. I. Neuman, B. Sarkar and co-workers.

中文翻译：

封面特征：Cobalt (III) Corrole 与 S-Bound DMSO 配体的合成和表征（Eur. J. Inorg. Chem. 35/2021）

封面特征显示了首次报道的 S 键合 DMSO 连接钴的分子结构，具有非常短的 Co-S 键长，以及用于多构型波函数计算的前沿轨道。这些表明来自 S 原子的 σ 供体效应是封闭壳基态构型的原因。作者将实验和理论技术紧密结合，以阐明该复合物的电子结构和光谱特性。更多信息可以在 N. I. Neuman、B. Sarkar 和同事的全文中找到。

更新日期：2021-09-15

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