Front Cover: Ligand Effects in Carbon−Boron Coupling Processes Mediated by σ-BH Platinum Complexes (Eur. J. Inorg. Chem. 35/2021),European Journal of Inorganic Chemistry

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Front Cover: Ligand Effects in Carbon−Boron Coupling Processes Mediated by σ-BH Platinum Complexes (Eur. J. Inorg. Chem. 35/2021)
European Journal of Inorganic Chemistry ( IF 2.2 ) Pub Date : 2021-08-24 , DOI: 10.1002/ejic.202100695
Pablo Ríos ₁ , Francisco José Fernández‐de‐Córdova ₁ , Javier Borge ₂ , Natalia Curado ₁ , Agustí Lledós ₃ , Salvador Conejero ₁

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The Front Cover shows the differences in reactivity of platinum complexes bearing different N-heterocyclic carbene (NHC) ligands. Both systems are able to forge carbon-boron bonds at low temperature through the initial formation of platinum σ-BH intermediates, but as the temperature increases the process can be reversible or not depending on the NHC ligand. I^tBuⁱPr systems can cleave the C−B bond but this process is not energetically feasible with IMes ligands. The authors thank the GEQO group of the Spanish Royal Chemical Society (RSEQ) for the invitation to contribute to the RSEQ-GEQO Prize Winners Special Collection and Valle Ojeda for the nice artwork. More information can be found in the Full Paper by A. Lledós, S. Conejero and co-workers.

中文翻译：

封面：σ-BH 铂配合物介导的碳-硼偶联过程中的配体效应（Eur. J. Inorg. Chem. 35/2021）

封面显示了带有不同 N-杂环卡宾 (NHC) 配体的铂配合物的反应性差异。两种系统都能够通过初始形成铂 σ-BH 中间体在低温下形成碳 - 硼键，但随着温度的升高，该过程是否可逆取决于 NHC 配体。I ^t Bu ⁱ Pr 系统可以裂解 C-B 键，但该过程对于 IMes 配体在能量上是不可行的。作者感谢西班牙皇家化学学会 (RSEQ) 的 GEQO 小组邀请为 RSEQ-GEQO 获奖者特别收藏和 Valle Ojeda 提供精美的艺术品。更多信息可以在 A. Lledós、S. Conejero 和同事的全文中找到。

更新日期：2021-09-15

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