Monatshefte für Chemie - Chemical Monthly ( IF 1.7 ) Pub Date : 2021-08-24 , DOI: 10.1007/s00706-021-02829-0 Mahsa Anvari 1 , Nasrin Shadjou 1
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A one-pot, highly efficient procedure was reported for the synthesis of 1,4-disubstituted 1,2,3-triazoles in water as a green solvent using Cu@KCC-1-NH-CS2 as a novel nanoreactor. Different methods such as Fourier transform infrared spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, and adsorption/desorption analysis (BET equation) have been used for the characterization of engineered nanocatalyst. High surface area (133 m2 g−1) and porous structure of the nanocatalyst, excellent catalytic performance in ecofriendly and green solvent with very short reaction times (5–20 min), easy work up, no use of toxic solvents, and suitable reusability of the catalyst are advantages of this presented work.
Graphic abstract
中文翻译：
掺杂在皱纹纤维状纳米二氧化硅中的铜纳米粒子作为合成 1,4-二取代 1,2,3-三唑水溶液的有效催化剂
报道了使用Cu@KCC-1-NH-CS 2作为新型纳米反应器在作为绿色溶剂的水中合成1,4-二取代1,2,3-三唑的一锅高效程序。不同的方法，如傅里叶变换红外光谱、场发射扫描电子显微镜、透射电子显微镜、能量色散 X 射线光谱和吸附/解吸分析（BET 方程）已被用于表征工程纳米催化剂。高表面积（133 m 2 g -1) 和纳米催化剂的多孔结构、在环保和绿色溶剂中具有极短的反应时间（5-20 分钟）的优异催化性能、易于处理、不使用有毒溶剂以及催化剂的适当可重复使用性是本研究的优点.
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