当前位置: X-MOL 学术Z. Anorg. Allg. Chem. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Front Cover: Aliovalent substitution in phosphide-based materials – Crystal structures of Na10AlTaP6 and Na3GaP2 featuring edge-sharing EP4 tetrahedra (E=Al/Ta and Ga) (Z. Anorg. Allg. Chem. 18/2021)
Zeitschrift für anorganische und allgemeine Chemie ( IF 1.1 ) Pub Date : 2021-08-23 , DOI: 10.1002/zaac.202100269
Tassilo M. F. Restle 1 , Sabine Zeitz 1 , Jan Meyer 1 , Wilhelm Klein 1 , Gabriele Raudaschl‐Sieber 2 , Antti J. Karttunen 3 , Thomas F. Fässler 1
Affiliation  

The cover picture shows sketches of the two novel structures emphasizing two of the manifold possibilities of tetrahedral building blocks. Na10AlTaP6 and Na3GaP2 comprise discrete edge-sharing [(Al/Ta)P4] and linear chains of edge-sharing 1[GaP4/2] tetrahedra, respectively. The overlap of the experimental and calculated Raman spectrum show for the crystallographically mixed Al/Ta site exclusively heteroatomic dimers. Thus the swinging of the units unfold the atom arrangement. Due to the dedication of this issue to the 80th birthday of Prof. Schnöckel, who has intensively studied tetrahedral compounds by Raman spectroscopy, we substituted on the cover the wavelength of the 785 nm laser beam (382 THz) used for the Raman experiment by the frequency of the first pitch (294 Hz) of a famous song (see article 202100149).
image


中文翻译:

封面:磷化物基材料中的异价取代 - Na10AlTaP6 和 Na3GaP2 的晶体结构具有共享边缘的 EP4 四面体(E=Al/Ta 和 Ga)(Z. Anorg. Allg. Chem. 18/2021)

封面图片显示了两种新颖结构的草图,强调了四面体积木的多种可能性。Na 10 AlTaP 6和Na 3 GaP 2 分别包括分立的共享边[(Al/Ta)P 4 ] 和共享边1 [GaP 4/2 ] 四面体的线性链。实验和计算的拉曼光谱的重叠显示了晶体混合的 Al/Ta 位点完全是杂原子二聚体。因此,单位的摆动展开原子排列。由于这个问题的奉献给 80 th Schnöckel 教授通过拉曼光谱深入研究了四面体化合物的生日,我们将用于拉曼实验的 785 nm 激光束 (382 THz) 的波长替换为第一个间距 (294 Hz) 的频率一首著名的歌曲(见文章 202100149)。
图片
更新日期:2021-09-21
down
wechat
bug