当前位置：
X-MOL 学术
›
Biomacromolecules
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Synthesis, Properties, and Applications of Bio-Based Cyclic Aliphatic Polyesters
Biomacromolecules ( IF 5.5 ) Pub Date : 2021-08-20 , DOI: 10.1021/acs.biomac.1c00638 Philip B Yang 1 , Matthew G Davidson 1 , Karen J Edler 1 , Steven Brown 2
Biomacromolecules ( IF 5.5 ) Pub Date : 2021-08-20 , DOI: 10.1021/acs.biomac.1c00638 Philip B Yang 1 , Matthew G Davidson 1 , Karen J Edler 1 , Steven Brown 2
Affiliation
|
Cyclic polymers have long been reported in the literature, but their development has often been stunted by synthetic difficulties such as the presence of linear contaminants. Research into the synthesis of these polymers has made great progress in the past decade, and this review covers the synthesis, properties, and applications of cyclic polymers, with an emphasis on bio-based aliphatic polyesters. Synthetic routes to cyclic polymers synthesized from bioderived monomers, alongside mechanistic descriptions for both ring closure and ring expansion polymerization approaches, are reviewed. The review also highlights some of the unique physical properties of cyclic polymers together with potential applications. The findings illustrate the substantial recent developments made in the syntheses of cyclic polymers, as well as the progress which can be made in the commercialization of bio-based polymers through the versatility this topology provides.
中文翻译：
生物基环状脂肪族聚酯的合成、性能及应用
环状聚合物长期以来一直在文献中报道，但它们的发展经常受到合成困难（例如线性污染物的存在）的阻碍。在过去十年中，这些聚合物的合成研究取得了很大进展，本综述涵盖了环状聚合物的合成、性质和应用，重点是生物基脂肪族聚酯。综述了由生物衍生单体合成的环状聚合物的合成路线，以及闭环和扩环聚合方法的机理描述。该评论还重点介绍了环状聚合物的一些独特物理特性以及潜在应用。这些发现说明了环状聚合物合成方面的最新进展，
更新日期：2021-09-13
中文翻译：
生物基环状脂肪族聚酯的合成、性能及应用
环状聚合物长期以来一直在文献中报道，但它们的发展经常受到合成困难（例如线性污染物的存在）的阻碍。在过去十年中，这些聚合物的合成研究取得了很大进展，本综述涵盖了环状聚合物的合成、性质和应用，重点是生物基脂肪族聚酯。综述了由生物衍生单体合成的环状聚合物的合成路线，以及闭环和扩环聚合方法的机理描述。该评论还重点介绍了环状聚合物的一些独特物理特性以及潜在应用。这些发现说明了环状聚合物合成方面的最新进展，
京公网安备 11010802027423号