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The structural and optical properties of GO: Temperature-dependent analysis of the electrical properties of Al/GO/p-type Si semiconductor structures
Journal of Physics and Chemistry of Solids ( IF 4.3 ) Pub Date : 2021-08-21 , DOI: 10.1016/j.jpcs.2021.110348
Niyazi Berk 1 , Halil Seymen 2 , İkram Orak 3 , Şükrü Karataş 1, 4
Affiliation  

A spin-coating process has been used to generate graphene oxide (GO) thin films on p-type silicon. The temperature-dependent basic electrical characteristics of Al/GO/p-type Si metal–semiconductor structures have been examined through current–voltage (IV) measurements in the temperature range 80–420 K by increments of 20 K based on thermionic emission (TE) theory. At each temperature, the main electrical parameters, such as ideality factor (n), rectification ratio (RR), saturation current (I0), barrier height (Φbo), and series resistance (RS), were determined. With increasing temperature, the values of n, I0, RR, and RS decreased, whereas the value of Φbo increased. These unusual temperature fluctuations in Φbo and n may be rationalized in terms of twofold Gaussian distributions at 80–200 K and 220–420 K. For the high- and low-temperature regions, evaluation of these two Gaussian distributions of the I–V curves for the Al/GO/p-type Si structure yielded mean barrier heights of 1.676 and 0.555 eV with standard deviations (σ0) of 166 mV and 76 mV, respectively. Modified ln(I0/T2)−(q2σs2)/(2k2T2) vs. q/(kT) plots, which correspond to these two separate temperature regions, further corroborated these barrier height values. The value of the Richardson constant (A*), 3.567 × 10−6 A K−2 cm−2, is substantially lower than the known value for p-Si. However, for the distribution in the 220–420 K region, the Richardson constant of 48.069 A K−2 cm−2 is near to the known theoretical value of 32 A K−2 cm−2 for p-type Si.



中文翻译:

GO的结构和光学特性:Al/GO/p型Si半导体结构电特性的温度相关分析

旋涂工艺已被用于在 p 型硅上生成氧化石墨烯 (GO) 薄膜。Al/GO/p 型 Si 金属-半导体结构的温度相关基本电学特性已通过电流-电压 ( IV ) 测量在 80-420 K 温度范围内通过基于热电子发射的 20 K 增量进行检查(TE) 理论。在每个温度下,确定了主要电气参数,例如理想因子 ( n )、整流比 (RR)、饱和电流 ( I 0 )、势垒高度 (Φ bo ) 和串联电阻 ( R S )。随着温度升高,n , I的值0 ,RR,和- [R小号下降,而Φ的值增加。Φ bon 的这些不寻常的温度波动可以根据 80-200 K 和 220-420 K 的双重高斯分布来合理化。对于高温和低温区域,评估I-V的这两个高斯分布Al/GO/p 型 Si 结构的平均势垒高度分别为 1.676 和 0.555 eV,标准偏差 ( σ 0 ) 分别为 166 mV 和 76 mV。修正 ln(I 0 /T 2 )−(q 2 σ s 2 )/(2k 2 T2 ) vs. q/(kT) 图,对应于这两个单独的温度区域,进一步证实了这些势垒高度值。理查森常数 ( A *)的值3.567 × 10 -6  A K -2 cm -2大大低于 p-Si 的已知值。然而,对于 220-420 K 区域的分布,48.069 A K -2 cm -2的理查森常数接近p 型 Si的已知理论值 32 A K -2 cm -2

更新日期:2021-08-27
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