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Improvement of interfacial contact for efficient PCBM/MAPbI3 planar heterojunction solar cells with a binary antisolvent mixture treatment
Nanotechnology ( IF 3.5 ) Pub Date : 2021-09-07 , DOI: 10.1088/1361-6528/ac1ec0
Anjali Chandel, Jia-Ren Wu, Diksha Thakur, Said Kassou, Shou-En Chiang, Kai-Jen Cheng, Chung-Yu Li, Yung-Sheng Yen, Sheng-Hui Chen, Sheng Hsiung Chang

Atomic-force microscopic images, x-ray diffraction patterns, Urbach energies and photoluminescence quenching experiments show that the interfacial contact quality between the hydrophobic [6,6]-phenyl-C61-buttric acid methyl ester (PCBM) thin film and hydrophilic CH3NH3PbI3 (MAPbI3) thin film can be effectively improved by using a binary antisolvent mixture (toluene:dichloromethane or chlorobenzene:dichloromethane) in the anti-solvent mixture-mediated nucleation process, which increases the averaged power conversion efficiency of the resultant PEDOT:PSS (P3CT-Na) thin film based MAPbI3 solar cells from 13.18% (18.52%) to 13.80% (19.55%). Beside, the use of 10% dichloromethane (DCM) in the binary antisolvent mixture results in a nano-textured MAPbI3 thin film with multicrystalline micrometer-sized grains and thereby increasing the short-circuit current density and fill factor (FF) of the resultant solar cells. It is noted that a remarkable FF of 80.33% is achieved, which can be used to explain the stable photovoltaic performance without additional encapsulations.



中文翻译:

通过二元反溶剂混合物处理改善高效 PCBM/MAPbI3 平面异质结太阳能电池的界面接触

原子力显微图像、X 射线衍射图、Urbach 能量和光致发光猝灭实验表明,疏水性 [6,6]-苯基-C 61-丁酸甲酯 (PCBM) 薄膜与亲水性 CH之间的界面接触质量3 NH 3碘化铅3(MAPbI 3在反溶剂混合物介导的成核过程,这增加的平均功率转换效率(二氯甲烷:二氯甲烷或氯苯甲苯))的薄膜可以有效地通过使用二进制反溶剂混合物改进所得 PEDOT:PSS (P3CT-Na) 薄膜基 MAPbI 3太阳能电池从 13.18% (18.52%) 到 13.80% (19.55%)。此外,在二元反溶剂混合物中使用 10% 二氯甲烷 (DCM) 会产生具有多晶微米级晶粒的纳米纹理 MAPbI 3薄膜,从而增加所得的短路电流密度和填充因子 (FF)太阳能电池。值得注意的是,实现了 80.33% 的显着 FF,这可以用来解释没有额外封装的稳定光伏性能。

更新日期:2021-09-07
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