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Photoluminescence Stability Enhancement of Ag–In–Ga–S/GaSx Core/Shell Quantum Dots with Thicker Shells by the Addition of Gallium Diethyldithiocarbamate
Chemistry Letters ( IF 1.4 ) Pub Date : 2021-08-18 , DOI: 10.1246/cl.210363 Watcharaporn Hoisang 1 , Taro Uematsu 1, 2 , Tsukasa Torimoto 3 , Susumu Kuwabata 1, 2
Chemistry Letters ( IF 1.4 ) Pub Date : 2021-08-18 , DOI: 10.1246/cl.210363 Watcharaporn Hoisang 1 , Taro Uematsu 1, 2 , Tsukasa Torimoto 3 , Susumu Kuwabata 1, 2
Affiliation
A spectrally narrow band edge emission is generated in the green region from cadmium-free quantum dots comprised of silver indium gallium sulfide coated by gallium sulfide shells. The thickness of the gallium sulfide shell is increased by using gallium tris(diethyldithiocarbamate) as a supplementary precursor showing a strong adhesion with the quantum dot cores. Photoluminescence intensity and spectral shape of the core/shell quantum dots with the thicker shells are unchanged after 90 days.
中文翻译:
通过添加二乙基二硫代氨基甲酸镓增强具有较厚壳的 Ag-In-Ga-S/GaSx 核/壳量子点的光致发光稳定性
无镉量子点在绿色区域产生光谱窄带边缘发射,量子点由硫化镓壳包覆的银铟镓硫化物组成。通过使用三(二乙基二硫代氨基甲酸)镓作为补充前驱体,增加了硫化镓壳的厚度,显示出与量子点核的强附着力。具有较厚壳的核/壳量子点的光致发光强度和光谱形状在 90 天后没有变化。
更新日期:2021-08-19
中文翻译:
通过添加二乙基二硫代氨基甲酸镓增强具有较厚壳的 Ag-In-Ga-S/GaSx 核/壳量子点的光致发光稳定性
无镉量子点在绿色区域产生光谱窄带边缘发射,量子点由硫化镓壳包覆的银铟镓硫化物组成。通过使用三(二乙基二硫代氨基甲酸)镓作为补充前驱体,增加了硫化镓壳的厚度,显示出与量子点核的强附着力。具有较厚壳的核/壳量子点的光致发光强度和光谱形状在 90 天后没有变化。