Abstract

A method for solving the inverse problem of chemical kinetics based on stationary data for chemical reactions proceeding according to nonideal kinetic laws in an isothermal gradientless reactor was developed. The estimation of the rates constants of reaction stages in terms of the Marcelin−de Donder kinetics different from mass action kinetics was exemplified. The results obtained expand the understanding of the possibility of solving the inverse problem of chemical kinetics by stationary data taking into account the influence of nonideal factors.

中文翻译：

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非理想动力学化学反应用稳态数据解反问题

摘要

针对在等温无梯度反应器中按照非理想动力学定律进行的化学反应，开发了一种基于稳态数据求解化学动力学逆问题的方法。举例说明了根据不同于质量作用动力学的 Marcelin-de Donder 动力学估计反应阶段的速率常数。所获得的结果扩展了对通过考虑非理想因素影响的平稳数据解决化学动力学逆问题的可能性的理解。