Achieving High Performance Metal–Organic Framework Materials through Pore Engineering,Accounts of Chemical Research

当前位置： X-MOL 学术 › Acc. Chem. Res. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Achieving High Performance Metal–Organic Framework Materials through Pore Engineering
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2021-08-17 , DOI: 10.1021/acs.accounts.1c00328
Rui-Biao Lin ₁ , Zhangjing Zhang ₂ , Banglin Chen ₃

Affiliation

Achieving high performance functional materials has been a long-term goal for scientists and engineers that can significantly promote science and technology development and thus benefit our society and human beings. As well-known porous materials, metal–organic frameworks (MOFs) are crystalline open frameworks made up of molecular building blocks linked by strong coordination bonds, affording pore space for storing and trapping guest molecules. In terms of porosity, MOFs outperform traditional porous materials including zeolites and activated carbon, showing exceptional porosity with internal surface area up to thousands of square meters per gram of sample and with periodic pore sizes ranging from sub-nanometer to nanometers. Numerous MOFs have been synthesized with potential applications ranging from storing gaseous fuels to separating intractable industrial gas mixtures, sensing physical and chemical stimulus, and transmitting protons for conduction. Compared to traditional porous materials, MOFs are distinguished for their exceptional capability for pore adjustment and interior modification through pore engineering, which have made them a preeminent platform for exploring functional materials with high performance.

中文翻译：

通过孔隙工程实现高性能金属-有机骨架材料

实现高性能功能材料一直是科学家和工程师的长期目标，可以显着促进科学技术的发展，从而造福我们的社会和人类。作为众所周知的多孔材料，金属有机骨架 (MOF) 是由通过强配位键连接的分子构建块组成的结晶开放骨架，为存储和捕获客体分子提供了孔隙空间。在孔隙率方面，MOFs 优于包括沸石和活性炭在内的传统多孔材料，显示出优异的孔隙率，每克样品的内表面积高达数千平方米，周期性孔径范围从亚纳米到纳米。许多 MOF 已被合成，其潜在应用范围从储存气体燃料到分离难处理的工业气体混合物、传感物理和化学刺激以及传输质子进行传导。与传统的多孔材料相比，MOFs以其通过孔工程进行孔调节和内部改性的卓越能力而著称，这使其成为探索高性能功能材料的卓越平台。

更新日期：2021-09-07

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11