Revisiting Alkane Hydroxylation with m-CPBA (m-Chloroperbenzoic Acid) Catalyzed by Nickel(II) Complexes,Chemistry - A European Journal

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Revisiting Alkane Hydroxylation with m-CPBA (m-Chloroperbenzoic Acid) Catalyzed by Nickel(II) Complexes
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2021-08-17 , DOI: 10.1002/chem.202102532
Tomoya Shinke ₁ , Mayu Itoh ₁ , Takuma Wada ₁ , Yuma Morimoto ₁ , Sachiko Yanagisawa ₂ , Hideki Sugimoto ₁ , Minoru Kubo ₂ , Shinobu Itoh ₁

Affiliation

Hydroxylation of alkanes with m-CPBA (m-chloroperbenzoic acid) catalyzed by Ni^II-complexes was investigated. Based on the detailed mechanistic studies, we propose that both (L)Ni^II−O^. and aroyloxyl radical species generated by the O−O bond homolysis of a (L)Ni^II-m-CPBA adduct a contribute to the hydrogen atom abstraction process from the substrates in the alkane hydroxylation reaction.

中文翻译：

用镍 (II) 配合物催化的 m-CPBA（间氯过苯甲酸）重新审视烷烃的羟基化反应

烷烃的羟基化与间- CPBA（米用Ni催化氯过苯甲酸）^II -complexes进行了研究。基于详细的机理研究，我们提出 (L)Ni ^II -O ^。和由 (L)Ni ^II - m -CPBA 加合物a的 O-O 键均裂产生的芳酰氧基自由基物种有助于从烷烃羟基化反应中的底物中提取氢原子的过程。

更新日期：2021-10-25

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