An Efficient Synthesis of Alkyl Dithiocarbamates through Michael-type Addition of Tetraalkylthiuram Disulfides to Electrophilic Alkenes,Asian Journal of Organic Chemistry

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An Efficient Synthesis of Alkyl Dithiocarbamates through Michael-type Addition of Tetraalkylthiuram Disulfides to Electrophilic Alkenes
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-08-16 , DOI: 10.1002/ajoc.202100435
Shuai Hao ₁ , Songshuang Ding ₁ , Zhiyong Wu ₂ , Haoyang Bi ₃ , Feng Bai ₃ , Xinling Yang ₃ , Longfei Wang ₁ , Yiying Wang ₁ , Hongtao Shen ₃ , Mingqin Zhao ₁

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A facile protocol for the synthesis of alkyl dithiocarbamates from electrophilic alkenes and tetraalkylthiuram disulfides has been achieved. The method proceeds smoothly under mild conditions without any metal catalysts and has a broad range of functional group tolerance.