The Effect of trans Axial Isocyanide Ligands on Iron(II) Tetra-NHC Complexes and their Reactivity in Olefin Epoxidation,Asian Journal of Organic Chemistry

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The Effect of trans Axial Isocyanide Ligands on Iron(II) Tetra-NHC Complexes and their Reactivity in Olefin Epoxidation
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2021-08-16 , DOI: 10.1002/ajoc.202100487
Eva-Maria Hélène Jeanne Esslinger ₁ , Jonas Felix Schlagintweit ₂ , Greta G. Zámbó ₂ , Alexander M. Imhof ₂ , Robert M. Reich ₂ , Fritz Elmar Kühn ₃

Affiliation

Two bio-inspired iron(II) complexes are applied in olefin epoxidation catalysis of cis-cyclooctene presenting low catalyst performance, but an exceptional high tolerance towards elevated temperatures through the replacement of trans axial labile acetonitrile ligands by π-accepting isocyanide ligands at the iron center.