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Manganese-Catalyzed Ammonia Oxidation into Dinitrogen under Chemical or Electrochemical Conditions**
ChemPlusChem ( IF 3.0 ) Pub Date : 2021-08-17 , DOI: 10.1002/cplu.202100349 Hiroki Toda 1 , Kaito Kuroki 1 , Ryoichi Kanega 2 , Shogo Kuriyama 1 , Kazunari Nakajima 3 , Yuichiro Himeda 2 , Ken Sakata 4 , Yoshiaki Nishibayashi 1
ChemPlusChem ( IF 3.0 ) Pub Date : 2021-08-17 , DOI: 10.1002/cplu.202100349 Hiroki Toda 1 , Kaito Kuroki 1 , Ryoichi Kanega 2 , Shogo Kuriyama 1 , Kazunari Nakajima 3 , Yuichiro Himeda 2 , Ken Sakata 4 , Yoshiaki Nishibayashi 1
Affiliation
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Manganese-catalyzed ammonia oxidation under chemical or electrochemical conditions is investigated in this work. Mechanistic studies including density functional theory (DFT) calculations revealed that a nucleophilic attack of ammonia on manganese imide complexes occurs to form a nitrogen–nitrogen bond leading to dinitrogen.
中文翻译：
化学或电化学条件下锰催化氨氧化成二氮**
本工作研究了化学或电化学条件下的锰催化氨氧化。包括密度泛函理论 (DFT) 计算在内的机理研究表明，氨对锰酰亚胺配合物的亲核攻击会形成氮-氮键，从而产生二氮。
更新日期：2021-08-17
中文翻译：
化学或电化学条件下锰催化氨氧化成二氮**
本工作研究了化学或电化学条件下的锰催化氨氧化。包括密度泛函理论 (DFT) 计算在内的机理研究表明，氨对锰酰亚胺配合物的亲核攻击会形成氮-氮键，从而产生二氮。
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