Inorganic and Nano-Metal Chemistry ( IF 1.4 ) Pub Date : 2021-08-16 , DOI: 10.1080/24701556.2021.1966456 Jiai Hua 1, 2 , Chaohui Yang 1 , Xiaoyu Zhang 1 , Nan Chen 1 , Bin Hu 1 , Yujian Bian 1 , Xiang Ma 1
Abstract
Selective adsorption of the CO2 in environment is an important research field of inorganic chemistry and coordination chemistry. A coordination polymer [Co2(tib)2(1,4-NDC)2]·7H2O (CTN) was composed by the reaction of 1,3,5-tris(1-imidazolyl) benzene (tib) and 1,4-naphthalenedicarboxylic acid (1,4-H2NDC) with Co2+ under solvothermal conditions. The result of X-ray single-crystal analysis shows that CTN is a twofold interpenetrating 3D framework with {42·65·83}{42·6} topology. CTN was further characterized by powder X-ray diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis. Notably, CTN possesses an excellent CO2 absorption property.
中文翻译:
具有选择性吸附二氧化碳的三维钴混合配体框架
摘要
环境中CO 2 的选择性吸附是无机化学和配位化学的一个重要研究领域。配位聚合物[Co 2 (tib) 2 (1,4-NDC) 2 ]·7H 2 O (CTN)由1,3,5-三(1-咪唑基)苯(tib)和1 ,4-萘二甲酸 (1,4-H 2 NDC) 与 Co 2+在溶剂热条件下。X射线单晶分析结果表明,CTN是一个具有{4 2 ·6 5 ·8 3 }{4 2·6}拓扑。CTN 通过粉末 X 射线衍射、红外光谱、热重分析和元素分析进一步表征。值得注意的是,CTN具有优异的CO 2吸收性能。