Photoelectron Photoion Coincidence Spectroscopy of NCl3 and NCl2,ChemPhysChem

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Photoelectron Photoion Coincidence Spectroscopy of NCl3 and NCl2
ChemPhysChem ( IF 2.3 ) Pub Date : 2021-08-14 , DOI: 10.1002/cphc.202100537
Marius Gerlach ₁ , Sophie Monninger ₁ , Domenik Schleier ₁ , Patrick Hemberger ₂ , James T Goettel ₃ , Holger Braunschweig ₃ , Ingo Fischer ₁

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An ion mass-selected threshold photoelectron spectrum of NCl₂ is reported. An ionization energy of 9.94±0.02 eV is derived from the spectrum. A vibrational progression in the symmetric stretching mode with ν₁=730 cm⁻¹ indicates a significant decrease in the N−Cl bond length.