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Fabrication of a GaAs/GaNAsBi solar cell and its performance improvement by thermal annealing
Semiconductor Science and Technology ( IF 1.9 ) Pub Date : 2021-07-29 , DOI: 10.1088/1361-6641/ac13af
Hiromu Kawata 1 , Sho Hasegawa 1 , Junta Matsumura 1 , Hiroyuki Nishinaka 2 , Masahiro Yoshimoto 2
Affiliation  

To evaluate the performance of GaNAsBi alloys as solar cell materials, a GaNAsBi double-heterostructure pin solar cell was fabricated using plasma-assisted solid source molecular beam epitaxy. The addition of even a small amount of N (less than 1%) to the GaAsBi alloy significantly reduces the short-circuit current density (J sc) of the solar cell. However, after thermal annealing, J sc increases by ∼6.5 times. After thermal annealing, the GaN0.006As0.966Bi0.028 solar cells (bandgap (E g) = 1.15 eV) exhibited an open-circuit voltage (V oc) of 0.35 V, J sc of 10.2 mA cm−2, and fill factor of 0.56. Based on the Urbach energy of Ga(N)AsBi, the decreased crystallinity associated with the addition of N leads to poor characteristics of GaNAsBi solar cells compared with those GaAsBi solar cells.



中文翻译:

GaAs/GaNAsBi太阳能电池的制备及其热退火性能提升

为了评估 GaNAsBi 合金作为太阳能电池材料的性能,使用等离子体辅助固体源分子束外延制造了 GaNAsBi 双异质结构 pin 太阳能电池。即使在 GaAsBi 合金中添加少量 N(小于 1%)也能显着降低太阳能电池的短路电流密度 ( J sc )。然而,在热退火后,J sc增加了约 6.5 倍。热退火后,GaN 0.006 As 0.966 Bi 0.028太阳能电池(带隙 ( E g ) = 1.15 eV)的开路电压 ( V oc ) 为 0.35 V,J sc为 10.2 mA cm−2,填充因子为 0.56。基于 Ga(N)AsBi 的 Urbach 能量,与那些 GaAsBi 太阳能电池相比,与添加 N 相关的结晶度降低导致 GaNAsBi 太阳能电池的特性较差。

更新日期:2021-07-29
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