ECS Journal of Solid State Science and Technology ( IF 1.8 ) Pub Date : 2021-08-05 , DOI: 10.1149/2162-8777/ac1997 Tianyu Lin , Tongtong Xuan , Rong-Jun Xie
Traditional synthesis of InP core/shell quantum dots (QDs) suffers from high cost, high toxicity, and difficulty due to the use of the expensive and highly toxic tris(trimethylsilyl)phosphine (P(TMS)3) as the phosphorus source. In this Perspective, we discuss advances in the design and synthesis of InP core/shell QDs using a cheap and low toxicity phosphorus source-tris(dimethylamino) phosphine (P(DMA)3) as well as their applications in QD light-emitting diodes (QLEDs). Finally, we address the remaining challenges in the synthesis, optical properties, and stability of InP core/shell QDs and the performance of their QLEDs.
中文翻译:
展望——使用三(二甲氨基)膦的高效磷化铟核/壳量子点的合成和发光二极管应用
InP核/壳量子点(QDs)的传统合成由于使用昂贵且剧毒的三(三甲基甲硅烷基)膦(P(TMS)3)作为磷源而面临高成本、高毒性和困难。在这个视角中,我们讨论了使用廉价和低毒性磷源三(二甲氨基)膦(P(DMA)3)设计和合成 InP 核/壳 QD 的进展及其在 QD 发光二极管中的应用(QLED)。最后,我们解决了 InP 核/壳 QD 的合成、光学特性和稳定性及其 QLED 性能方面的剩余挑战。