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Mastering mono-bond metathesis
Nature Chemistry ( IF 19.2 ) Pub Date : 2021-08-13 , DOI: 10.1038/s41557-021-00754-7 Michael M Gilbert 1 , Daniel J Weix 1
Nature Chemistry ( IF 19.2 ) Pub Date : 2021-08-13 , DOI: 10.1038/s41557-021-00754-7 Michael M Gilbert 1 , Daniel J Weix 1
Affiliation
Carbon–carbon single bonds are generally among the least reactive chemical bonds. While olefin metathesis reactions are well established, direct metathesis of C–C single bonds is rare. Now, a C–C single bond metathesis reaction has been developed, forming cross-biaryl products from unstrained homo-biaryl compounds.
中文翻译:
掌握单键复分解
碳-碳单键通常是反应性最低的化学键之一。虽然烯烃复分解反应已经很成熟,但 C-C 单键的直接复分解很少见。现在,已经开发出 C-C 单键复分解反应,从无应变的均联芳基化合物形成交叉联芳基产物。
更新日期:2021-08-13
中文翻译:
掌握单键复分解
碳-碳单键通常是反应性最低的化学键之一。虽然烯烃复分解反应已经很成熟,但 C-C 单键的直接复分解很少见。现在,已经开发出 C-C 单键复分解反应,从无应变的均联芳基化合物形成交叉联芳基产物。