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The influence of Ga doping on preparation and thermoelectric properties of flexible Ag2Se films
Composites Communications ( IF 6.5 ) Pub Date : 2021-08-12 , DOI: 10.1016/j.coco.2021.100895
Yiming Lu 1 , Ying Liu 1 , Yating Li 1 , Kefeng Cai 1
Affiliation  

Herein, we prepared Ga doped Ag2Se flexible films on porous nylon membrane. First, Se nanowires (NWs) were wet chemically synthesized, then different amounts of Ga doped Ag2Se (Ag2-xGaxSe, x = 0.01, 0.02, 0.04) NWs were prepared using the Se NWs as templates in solution at 80 °C, and finally the Ga doped Ag2Se films on porous nylon membrane were fabricated by vacuum assisted filtration and then hot pressing at 230 °C and 1 MPa for 30 min. The Ag1.98Ga0.02Se film exhibits a higher power factor of ~1162 μW m−1 K−2 at 300 K and a superior flexibility: after bending for 1000 cycles around a 4-mm-radius rod, about 97% of the initial electrical conductivity is maintained.



中文翻译:

Ga掺杂对Ag2Se柔性薄膜制备及热电性能的影响

在此,我们在多孔尼龙膜上制备了 Ga 掺杂的 Ag 2 Se 柔性薄膜。首先,硒纳米线(NWS)是湿的化学合成,然后不同量的Ga掺杂的Ag 2硒(AG 2- XX SE,X  = 0.01,0.02,0.04)纳米线,使用硒纳米线作为在溶液制备的模板80 °C,最后通过真空辅助过滤在多孔尼龙膜上制备Ga 掺杂的 Ag 2 Se 膜,然后在 230 °C 和 1 MPa 下热压 30 分钟。Ag 1.98 Ga 0.02 Se 薄膜表现出更高的功率因数,约为 1162 μW m -1  K -2 在 300 K 和出色的柔韧性下:围绕 4 毫米半径的棒弯曲 1000 次循环后,大约 97% 的初始导电率保持不变。

更新日期:2021-08-15
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