CuCe_0.8La_0.1Sm_0.1O_2-δ and CuCe_0.8Nd_0.1Sm_0.1O_2-δ are studied as anode materials for solid oxide fuel cells with methanol as fuel. The oxygen surface exchange and bulk diffusion coefficients of Ce_0.8Sm_0.2O_2-δ both increase with La and Nd doping. The CH₃OH temperature-programmed surface reaction results show that the addition of La and Nd accelerates the chemical oxidation of CH₃OH. Furthermore, compared with CuCe_0.8Sm_0.2O_2-δ, the anodes with La and Nd show higher resistance to coking in CH₃OH atmosphere. The Cu-based cermet anode exhibits a low catalytic activity for the electrochemical oxidation of H₂, and a single cell supported by a Ce_0.8Sm_0.2O_2-δ‑carbonate composite electrolyte with CuCe_0.8Sm_0.2O_2-δ anode exhibits a maximum power density of 160 mW cm⁻² at 650 °C using dry hydrogen as fuel. However, the maximum power density reaches 550 mW cm⁻² when CH₃OH is used as fuel, and further increases to 730 and 830 mW cm⁻² with the addition of La and Nd in the anode, respectively. The results indicate that with the promotion of the oxygen activity, the Cu-based cermet is a promising anode material for solid oxide fuel cells using CH₃OH as fuel.

Cu Ce _0.8 La _0.1 Sm _0.1 O _2-δ和Cu Ce _0.8 Nd _0.1 Sm _0.1 O _2-δ被研究作为以甲醇为燃料的固体氧化物燃料电池的阳极材料。Ce _0.8 Sm _0.2 O _2-δ的氧表面交换和体扩散系数都随着La和Nd的掺杂而增加。CH ₃ OH程序升温表面反应结果表明，La和Nd的加入加速了CH ₃ OH的化学氧化。此外，与 Cu Ce _0.8 Sm _{0.2 相比}O _2-δ，具有La和Nd的阳极在CH ₃ OH气氛中表现出更高的抗结焦性。Cu基金属陶瓷阳极对H ₂的电化学氧化表现出低催化活性，由Ce _0.8 Sm _0.2 O _2-δ-碳酸盐复合电解质支撑的单电池与Cu Ce _0.8 Sm _0.2 O _2-δ阳极表现出使用干氢作为燃料，在 650°C 下的最大功率密度为 160 mW cm ^-2。然而，当CH ₃ OH用作燃料时，最大功率密度达到550 mW cm ^-2，并进一步增加到730和830 mW cm ^-2分别在阳极中添加 La 和 Nd。结果表明，随着氧活性的提高，Cu基金属陶瓷是一种很有前途的以CH ₃ OH为燃料的固体氧化物燃料电池的负极材料。