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Non-aqueous cross hydrolysis: an epoxide-free sol-gel route toward highly porous alumina monoliths
Journal of Sol-Gel Science and Technology ( IF 2.3 ) Pub Date : 2021-08-11 , DOI: 10.1007/s10971-021-05595-x
Simon Carstens 1 , Igor Atanasov 1 , Tim Jähnichen 1 , Dirk Enke 1 , Bastian Oberleiter 2
Affiliation  

Highly porous alumina monoliths can be fabricated by simultaneous hydrolysis of aluminum alkoxides and salts as homonuclear precursors. The use of carcinogenic epoxides can thus be avoided. In this novel approach, no water is added to the system but hydrolysis is induced by the crystal water of the aluminum salt. Mechanical stabilization and significantly increased porosity values can be achieved when the sol-gel synthesis is performed in an autoclave.



中文翻译:

非水交叉水解:一种不含环氧化物的溶胶-凝胶途径,用于制备高多孔氧化铝整料

高度多孔的氧化铝整料可以通过同时水解作为同核前体的铝醇盐和盐来制造。因此可以避免使用致癌环氧化物。在这种新方法中,系统中不加水,但水解是由铝盐的结晶水引起的。当溶胶-凝胶合成在高压釜中进行时,可以实现机械稳定性和显着增加的孔隙率值。

更新日期:2021-08-11
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