Contemporary macrocycles for discrete polymetallic complexes: precise control over structure and function,Chemical Society Reviews

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Contemporary macrocycles for discrete polymetallic complexes: precise control over structure and function
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2021-08-11 , DOI: 10.1039/d1cs00225b
Mohammad T Chaudhry ₁ , Shigehisa Akine _{2,

3} , Mark J MacLachlan _{1,

2,

4}

Affiliation

The growth of multimetallic clusters and complexes can proceed in the presence of suitable ligands, but often leads to polydisperse structures with poor solubility. As an alternative approach, macrocyclic molecules can anchor the multimetallic complex, directing its formation and stabilizing the resulting product. This approach can provide excellent control over the growth of clusters, and offers a handle to control solubility and other properties of the resulting complexes. In this Tutorial Review, we discuss recent activity (primarily the last two decades) directed at the controlled and reproducible synthesis of multimetallic complexes using macrocyclic ligands. Throughout the review, we focus on the unusual structures that are only accessible by using macrocycles as ligands, and their unique properties.

中文翻译：

离散多金属配合物的当代大环：对结构和功能的精确控制

多金属簇和配合物的生长可以在合适的配体存在下进行，但通常会导致溶解度差的多分散结构。作为替代方法，大环分子可以锚定多金属配合物，指导其形成并稳定所得产物。这种方法可以很好地控制簇的生长，并提供控制所得复合物的溶解度和其他特性的方法。在本教程回顾中，我们讨论了最近的活动（主要是过去二十年），旨在使用大环配体可控和可重复地合成多金属配合物。在整个审查过程中，我们专注于仅通过使用大环作为配体才能获得的不寻常结构及其独特性质。

更新日期：2021-08-11

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