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Synthesis and Study of Sorption, Antioxidant and Antibacterial Properties of MOF based on Cobalt Terephthalate and 1,10-Phenanthroline
Journal of Inorganic and Organometallic Polymers and Materials ( IF 3.9 ) Pub Date : 2021-08-11 , DOI: 10.1007/s10904-021-02087-x
Igor E. Uflyand 1 , Vladimir A. Zhinzhilo 1 , Julia D. Bryantseva 1
Affiliation  

MOF based on cobalt terephthalate and 1,10-phenanthroline was synthesized according to a modified procedure by the interaction of cobalt nitrate, terephthalic acid, and 1,10-phenanthroline in the presence of alkali. MOF has been used to extract the organic Congo red and methylene blue dyes from their aqueous solutions. The degree of removal depends on temperature and reaches values close to 100% within 60 min at 291 and 308 K. The limiting adsorption is 40 mg/g, and the Langmuir model is in good agreement with the experimental results. The antioxidant activity of MOF was evaluated on a model solution of adrenalin hydrochloride in an alkaline medium with a maximum inhibition of the oxidation of the model compound of 87.05%. The antibacterial activity of MOF against Escherichia coli (E. coli) was assessed as satisfactory, which is explained by the release of metal cations and organic ligand, and the long period of action is due to their synergistic action.



中文翻译:

基于对苯二甲酸钴和1,10-菲咯啉的MOF吸附、抗氧化和抗菌性能的合成与研究

基于对苯二甲酸钴和 1,10-菲咯啉的 MOF 是根据改进的程序通过硝酸钴、对苯二甲酸和 1,10-菲咯啉在碱存在下的相互作用合成的。MOF 已被用于从水溶液中提取有机刚果红和亚甲蓝染料。去除程度取决于温度,并在 291 和 308 K 下在 60 分钟内达到接近 100% 的值。极限吸附为 40 mg/g,Langmuir 模型与实验结果非常吻合。MOF 的抗氧化活性在碱性介质中的盐酸肾上腺素模型溶液上进行评估,最大抑制模型化合物的氧化为 87.05%。MOF 对大肠杆菌E.coli) 被评估为令人满意,这是由金属阳离子和有机配体的释放所解释的,而长期作用是由于它们的协同作用。

更新日期:2021-08-11
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