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Formulation of a paste for copper thick film
Journal of Nanoparticle Research ( IF 2.5 ) Pub Date : 2021-08-08 , DOI: 10.1007/s11051-021-05300-7
Jiayu Tang 1 , Cheuk Hei Herry Mak 1 , Sze Kee Tam 1 , Ka Ming Ng 1
Affiliation  

Conductive copper paste is a promising material for use in electronic devices, replacing silver or other metal pastes, because of its high conductivity, low electro-migration, and cost. However, the high sintering temperature and the need of an inert sintering atmosphere limit the commercial application of copper paste. In this study, a copper thick film paste for use on alumina was developed using a mixture of copper nanoparticles (50 nm in size) and microparticles (1 μm in size). With this paste, the sintering temperature was as low as 500 °C when the pressure was at ambient pressure. It was found that the bimodal copper film offered the best volume resistivity of 6.26 × 10−8 Ω·m at a weight ratio of micro- to nanoparticles of 2:1. Glass frits were used as an additive to improve the adhesion strength between the copper film and the alumina substrate with minimal change in electrical performance.



中文翻译:

铜厚膜浆料的配制

导电铜浆是一种很有前途的材料,可用于电子设备,替代银或其他金属浆,因为它具有高导电性、低电迁移和成本。然而,高烧结温度和惰性烧结​​气氛的需要限制了铜浆的商业应用。在这项研究中,使用铜纳米颗粒(尺寸为 50 nm)和微粒(尺寸为 1 μm)的混合物开发了一种用于氧化铝的铜厚膜浆料。当压力为环境压力时,使用这种浆料,烧结温度低至 500 °C。发现双峰铜膜提供了最好的体积电阻率 6.26 × 10 -8Ω·m,微米与纳米粒子的重量比为 2:1。玻璃料用作添加剂以提高铜膜和氧化铝基板之间的粘合强度,同时电气性能的变化最小。

更新日期:2021-08-09
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