Visible-Light-Promoted Selenocyanation of Cyclobutanone Oxime Esters Using Potassium Selenocyanate,The Journal of Organic Chemistry

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Visible-Light-Promoted Selenocyanation of Cyclobutanone Oxime Esters Using Potassium Selenocyanate
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2021-08-09 , DOI: 10.1021/acs.joc.1c00893
Xia Zhao ₁ , Liangshuo Ji ₁ , Yu Gao ₁ , Tengteng Sun ₁ , Jiamin Qiao ₁ , Ankun Li ₁ , Kui Lu ₂

Affiliation

We report the visible-light-promoted selenocyanation of cyclobutanone oxime esters using potassium selenocyanate in the presence of a fac-Ir(ppy)₃ catalyst for the first time. Because of the mild conditions employed and use of readily accessible potassium selenocyanate, this method is an effective and green strategy for the synthesis of cyano and selenocyano bifunctional substituted alkanes.

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