Metal–organic frameworks containing uncoordinated nitrogen: Preparation, modification, and application in adsorption,Materials Today

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Metal–organic frameworks containing uncoordinated nitrogen: Preparation, modification, and application in adsorption
Materials Today ( IF 21.1 ) Pub Date : 2021-08-08 , DOI: 10.1016/j.mattod.2021.07.021
Dong Kyu Yoo ₁ , Imteaz Ahmed ₁ , Mithun Sarker ₂ , Hye Jin Lee ₁ , Ajayan Vinu ₃ , Sung Hwa Jhung ₁

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Significant progress has been made on metal–organic frameworks (MOFs), especially those with functional groups like amines or carboxylic acid groups. MOFs with uncoordinated nitrogen (UCN-MOFs) are attractive for many applications (owing to Lewis basicity and possible coordination) and for possible further modifications to have other functionalities. In this review, recent progress on the preparation, modification for other functionalities, and applications (mainly in adsorption) of UCN-MOFs with or without modification will be discussed. The prospects in the relevant fields are suggested.

中文翻译：

含不配位氮的金属有机骨架材料的制备、改性及其在吸附中的应用

金属有机框架（MOF），特别是带有胺或羧酸基团等官能团的框架，已经取得了重大进展。具有不配位氮的 MOF（UCN-MOF）对于许多应用都很有吸引力（由于路易斯碱性和可能的配位），并且可能进一步修饰以具有其他功能。在这篇综述中，将讨论修饰或未修饰的UCN-MOFs的制备、其他功能的修饰以及应用（主要是吸附）方面的最新进展。并对相关领域的前景进行了展望。

更新日期：2021-08-08

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